authors |
Paz, FAA; Sousa, FL; Soares-Santos, PCR; Cavaleiro, AMV; Nogueira, HIS; Klinowski, J; Trindade, T |
nationality |
International |
journal |
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE |
keywords |
CRYSTAL-STRUCTURES; STRUCTURAL-CHARACTERIZATION; SUPERMOLECULAR COMPOUND; ACID; COMPLEXES |
abstract |
The structure of the title compound, tris(hydroxonium) mu(12)-phosphato-tetracosa-mu(2)-oxo-dodecaoxododecatungsten hexakis(benzo-15-crown-5)-methanol-water (1/1/1), (H3O)(3)[PW12O40].6C(14)H(20)O(5).CH3OH.H2O (where C14H20O5 is benzo-15-crown-5), has been determined at 180 K. [PW12O40](3-) anions are typical of alpha-Keggin structures, and the [H3O.(C14H20O5)(2)](+) sandwich-type moieties contain a large number of short O...O close contacts, suggesting strong hydrogen bonding within them. |
publisher |
BLACKWELL MUNKSGAARD |
issn |
1600-5368 |
year published |
2004 |
volume |
60 |
beginning page |
M1 |
ending page |
M5 |
digital object identifier (doi) |
10.1107/S1600536803024310 |
web of science category |
Crystallography |
subject category |
Crystallography |
unique article identifier |
WOS:000187552200005
|