abstract
A novel 3-D cuprous chloride polymer [Cu-2(I) Cl( mu 5-L)]n (1, HL = 1-tetrazole-4-imidazole-benzene) has been hydrothermally synthesized and structurally characterized. 1 displays a 3-D network with a bimodal fsc-3,5-Cmce-2 topological type constructed by the linkages of rare [(Cu2Cl)-Cl-I](+) cations and L- ligands. The photoluminescence properties and density functional theory calculations of 1 have also been studied.
keywords
COPPER(I) COORDINATION POLYMERS; METAL-ORGANIC FRAMEWORKS; THERMOCHROMIC-LUMINESCENCE; STRUCTURAL-CHARACTERIZATION; TETRAZOLE CLUSTERS; CRYSTAL-STRUCTURES; IODIDE CLUSTERS; LIGAND; COMPLEXES; NETWORKS
subject category
Chemistry
authors
Tang, QL; Zhou, J; Paz, FAA; Fu, LS; Xiao, H; Zhou, Q; Li, J
our authors
Filipe Alexandre Almeida Paz
Principal Researcher
Lianshe Fu
Assistant Researcheracknowledgements
This work was supported by the NNSF of China (no. 21671029), the NSF of Chongqing Municipality (no. cstc2014jcyjA50002, cstc2015jcyjBX0117), Program for Excellent Talents in Chongqing Higher Education Institutions, Fundacao para a Ciencia e a Tecnologia (FCT, Portugal), the European Union, QREN, FEDER through Programa Operacional Factores de Competitividade (COMPETE), and CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (FCT Ref. UID/CTM/50011/2013), financed by national funds through the FCT/MEC and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement. The authors are also grateful to Chongqing Normal University for financial support (14CSLJ02, 13XLZ07) and the Innovative Training Program of University Student (no. 201510637018).