CpMo(CO)(3)Cl as a precatalyst for the epoxidation of olefins
authors Valente, AA; Seixas, JD; Goncalves, IS; Abrantes, M; Pillinger, M; Romao, CC
nationality International
journal CATALYSIS LETTERS
author keywords molybdenum; organometallic oxides; oxidative decarbonylation; olefin epoxidation; tert-butyl hydroperoxide
keywords DIOXOMOLYBDENUM(VI) COMPLEXES; ORGANOMETALLIC OXIDES; MAIN-GROUP; CATALYSTS; MOLYBDENUM; ELEMENTS; ALKYL
abstract The tricarbonyl complex CpMo(CO)(3)C1 was found to act as a precatalyst for the reaction of tert-butyl hydroperoxide and olefins to yield the corresponding epoxides and diols. Under the reaction conditions, oxidative decarbonylation leads to the formation of the dioxo complex CpMoO2Cl. The catalytic recyclability and the effect of temperature on the catalytic results have been examined, and a reaction mechanism proposed, supported by kinetic modelling.
publisher SPRINGER
issn 1011-372X
year published 2005
volume 101
issue 1-2
beginning page 127
ending page 130
digital object identifier (doi) 10.1007/s10562-004-3760-y
web of science category Chemistry, Physical
subject category Chemistry
unique article identifier WOS:000228549400021
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journal analysis (jcr 2019):
journal impact factor 2.482
5 year journal impact factor 2.555
category normalized journal impact factor percentile 43.082
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