CpMo(CO)(3)Cl as a precatalyst for the epoxidation of olefins
| authors | Valente, AA; Seixas, JD; Goncalves, IS; Abrantes, M; Pillinger, M; Romao, CC |
| nationality | International |
| journal | CATALYSIS LETTERS |
| author keywords | molybdenum; organometallic oxides; oxidative decarbonylation; olefin epoxidation; tert-butyl hydroperoxide |
| keywords | DIOXOMOLYBDENUM(VI) COMPLEXES; ORGANOMETALLIC OXIDES; MAIN-GROUP; CATALYSTS; MOLYBDENUM; ELEMENTS; ALKYL |
| abstract | The tricarbonyl complex CpMo(CO)(3)C1 was found to act as a precatalyst for the reaction of tert-butyl hydroperoxide and olefins to yield the corresponding epoxides and diols. Under the reaction conditions, oxidative decarbonylation leads to the formation of the dioxo complex CpMoO2Cl. The catalytic recyclability and the effect of temperature on the catalytic results have been examined, and a reaction mechanism proposed, supported by kinetic modelling. |
| publisher | SPRINGER |
| issn | 1011-372X |
| year published | 2005 |
| volume | 101 |
| issue | 1-2 |
| beginning page | 127 |
| ending page | 130 |
| digital object identifier (doi) | 10.1007/s10562-004-3760-y |
| web of science category | Chemistry, Physical |
| subject category | Chemistry |
| unique article identifier | WOS:000228549400021 |
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impact metrics
| journal analysis (jcr 2019): |
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| journal impact factor | 2.482 |
| 5 year journal impact factor | 2.555 |
| category normalized journal impact factor percentile | 43.082 |
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