The first one-dimensional lanthanopolyoxotungstoborate

abstract

A novel one-dimensional zigzag lanthanopolyoxotungstoborate, H-2(NH4)(10)[Ce-2(BW11O39)(2)(H2O)(6)]- 21H(2)O, was synthesised under ambient conditions. It is the first example of a one-dimensional polymer where Keggin-type anions containing a central boron atom are bridged by Ce3+ cations. (c) 2005 Elsevier B.V. All rights reserved.

keywords

LANTHANIDE ELEMENTS; COMPLEXES; POLYOXO; ANIONS; LN

subject category

Chemistry

authors

Sousa, FL; Paz, FAA; Granadeiro, CMCE; Cavaleiro, AMV; Rocha, J; Klinowski, J; Nogueira, HIS

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