Designing novel organic-inorganic frameworks

abstract

Crystal engineering of coordination frameworks is a topical and rapidly advancing field, and a variety of entirely new solid materials have been synthesized. We describe the main challenges involved in the hydrothermal approach to these materials using, as an example, cadmium- and zinc-based coordination frameworks. We discuss the unusual crystal architectures of the products, and show that the kind and quality of the resulting crystals are directly controlled by the composition of the ternary reactive mixture and the temperature regime used in the hydrothermal synthesis.

keywords

3-HYDROXYPICOLINIC ACID HPICOH; X-RAY-DIFFRACTION; HYDROTHERMAL SYNTHESIS; TRIMESIC ACID; COORDINATION POLYMER; STRUCTURAL-CHARACTERIZATION; SUPRAMOLECULAR ISOMERISM; MAGNETIC-PROPERTIES; CHEMISTRY; COMPLEX

subject category

Chemistry

authors

Paz, FAA; Klinowski, J

our authors

Share this project:

Related Publications

We use cookies for marketing activities and to offer you a better experience. By clicking “Accept Cookies” you agree with our cookie policy. Read about how we use cookies by clicking "Privacy and Cookie Policy".