New Crystalline Layered Zinc Phosphate with 10-Membered-Ring Channels Perpendicular to Layers

abstract

A novel layered zinc phosphate, [N(2)C(6)H(12)](2)[Zn(7)H(3)(HPO(4-x))(5)(PO(4))(3)] H(2)O, with unique 10-membered-ring ellipsoidal channels running perpendicularly to ladder-shaped tetrahedral layers, has been synthesized ionothermally via in situ generation of 1,4-diazabicyclo[2.2.2] octane.

keywords

IONOTHERMAL SYNTHESIS; FRAMEWORKS

subject category

Chemistry

authors

Liu, L; Ferdov, S; Coelho, C; Kong, Y; Mafra, L; Li, JP; Dong, JX; Kolitsch, U; Ferreira, RAS; Tillmanns, E; Rocha, J; Lin, Z

our authors

acknowledgements

The Chinese group was financially supported by the National Natural Science Foundation of China (Grant 20573077) and the Special Program for Key Basic Research of the Ministry of Science and Technology, China. (Grant 2007CB616914). The Portuguese group was financially supported by FCT, POCI2010, PTDC, FSE, and FEDER.

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