(2,2 '-Bipyridine-kappa N-2,N ')chlorido(1,4,7-trithiacyclononane-kappa S-3,S ',S '')ruthenium(II) nitrate monohydrate
authors Fernandes, JA; Paz, FAA; Mota, MJP; Braga, SS; Santos, TM
nationality International
journal ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
keywords STRUCTURAL-CHARACTERIZATION; CYCLODEXTRINS; COMPLEXES
abstract In the title compound, [RuCl(C10H8N2)(C6H12S3)]NO3 center dot H2O or [RuCl(bpy)([9]aneS(3))]NO3 center dot H2O, ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2'-bipyridine), the Ru-II cation has a slightly distorted octahedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water molecule of crystallization are engaged in O-H center dot center dot center dot O hydrogen-bonding interactions, leading to a supramolecular chain running parallel to the c axis.
publisher WILEY-BLACKWELL
issn 1600-5368
year published 2010
volume 66
beginning page M1575
ending page U868
digital object identifier (doi) 10.1107/S1600536810046556
web of science category Crystallography
subject category Crystallography
unique article identifier WOS:000284831000061
  ciceco authors
  impact metrics
dimensions (citation analysis):
altmetrics (social interaction):



 


Sponsors

1suponsers_list_ciceco.jpg