authors |
Abdelhameed, RM; Ananias, D; Silva, AMS; Rocha, J |
nationality |
International |
journal |
CHEMISTRYSELECT |
author keywords |
Luminescence; Metal-Organic Frameworks; Optical centre; Post-synthetic modification |
keywords |
LANTHANIDE COMPLEXES; WHITE-LIGHT |
abstract |
Ln(3+)-bearing Metal-Organic Frameworks (MOFs) are attracting much attention because of their unique luminescence properties and the possibility of fine-tuning the metal coordination spheres by post-synthetic modification (PSM). Here, we report PSM of the well-known IRMOF-3 by reaction with methyl 3chloro-3-oxopropanoate and pyridine-2,6-dicarbonyl dichloride affording, respectively, IRMOF-3-CM and IRMOF-3-PY. (HNMR)-H-1 of the digested modified samples showed ca. 100% conversion of the amino group. The pendant groups of PSM IRMOF-3 were subsequently used to coordinate Eu+3 and Tb3+ and the luminescence properties of the materials studied. |
publisher |
WILEY-V C H VERLAG GMBH |
issn |
2365-6549 |
year published |
2017 |
volume |
2 |
issue |
1 |
beginning page |
136 |
ending page |
139 |
digital object identifier (doi) |
10.1002/slct.201601751 |
web of science category |
Chemistry, Multidisciplinary |
subject category |
Chemistry |
unique article identifier |
WOS:000395434600018
|