From Single-Molecule Precursors to Hybrid ZnS Nanostructures
authors Pereira, AS; Rauwel, P; Martins, MA; Trindade, T
nationality International
journal JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
author keywords Nanostructures; Zinc Sulfide; Metal Dithiocarbamato Complexes; Hybrid Materials
keywords LOW-TEMPERATURE SYNTHESIS; RAY CRYSTAL-STRUCTURES; OPTICAL-PROPERTIES; PHASE-CONTROL; QUANTUM DOTS; NANOCRYSTALS; NANOPARTICLES; DEPOSITION; NANOSHEETS; COMPLEXES
abstract A series of coordination compounds containing [Zn(amine)](2+) cationic complexes and alkyldithio-carbamates (RR'dtc(-)), as counter anions, are reported here: [Zn(amine)(x)][RR'dtc](2), where amine = ethylenediamine (en), diethylenetriamine (dien), 1,2-diaminopropane (dap) and, R,R' = ethyl (Et); butyl (Bu) and methyl (Me), hexyl (Hex). Hybrid nanoplates composed of hexagonal-ZnS nanoparticles and organic components were obtained after solution phase thermolysis of such precursors in oleylamine. These hybrid materials show quantum confinement effects in their optical spectra and convert into cubic-ZnS after further thermal treatment.
publisher AMER SCIENTIFIC PUBLISHERS
issn 1533-4880
year published 2010
volume 10
issue 4
beginning page 2768
ending page 2775
digital object identifier (doi) 10.1166/jnn.2010.1403
web of science category Chemistry, Multidisciplinary; Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter
subject category Chemistry; Science & Technology - Other Topics; Materials Science; Physics
unique article identifier WOS:000273984900078
  ciceco authors
  impact metrics
journal analysis (jcr 2019):
journal impact factor 1.134
5 year journal impact factor 0.999
category normalized journal impact factor percentile 17.801
dimensions (citation analysis):
altmetrics (social interaction):



 


Sponsors

1suponsers_list_ciceco.jpg