abstract
Owing to the competition between the radiative and nonradiative decay channels occurring in plasmonic assemblies, we show here how to conceive a long pass emission filter and actually design it. We report the synthesis of gold@silica nanoparticles grafted with dye molecules. The control of the thickness of the silica shell allows us to tune the distance between the metal core and the dye molecules. Assemblies of small number (1 to 7) of these core-shell (CS) particles, considered as multimers, have also been produced for the first time. We show that the shaping of the emission spectra of the multimers is drastically enhanced by comparison with the corresponding monomers. We also show a strong enhancement of the decay rates at the LSP resonance, dominated by the non-radiative energy tranfer from the active medium to the metal. The decay rates decrease as the detuning between the long wavelength emission and the LSP resonance increases. (C) 2011 Optical Society of America
keywords
SINGLE-MOLECULE FLUORESCENCE; GOLD NANOPARTICLES; QUANTUM DOTS; PARTICLES; FLUOROPHORES; LUMINESCENCE; SURFACES; COLLOIDS; SPHERES; LIGHT
subject category
Optics
authors
Ferrie, M; Pinna, N; Ravaine, S; Vallee, RAL
our authors
Nicola Pinna
ResearcherGroups
acknowledgements
The authors acknowledge le Conseil Regional d'Aquitaine and the European Research Network FAME for the Ph.D scholarship of Melanie Ferrie. Hassan Saadaoui is thanked for AFM measurements.