On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide

abstract

The formation of 1-butyl-3-methylimidazolium-2-carboxylate in the mixture of CO2 with 1-butyl-3-methylimidazolium acetate under mild conditions (298 K, 0.1 MPa) has been put in evidence in the liquid phase using Raman and infrared spectroscopy complemented by DFT calculations and NMR (H-1, C-13, N-15) spectroscopy.

keywords

TEMPERATURE IONIC LIQUIDS; PHASE-BEHAVIOR; CO2

subject category

Chemistry

authors

Besnard, M; Cabaco, MI; Chavez, FV; Pinaud, N; Sebastiao, PJ; Coutinho, JAP; Danten, Y

our authors

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