Making Prussian blue analogues nanoparticles luminescent: effect of the luminophore confinement over the properties

resumo

In this communication, we report the post-synthetic functionalization of K+/Ni2+/[Cr( CN) 6] 3-Prussian blue analogue (PBA) nanoparticles by the 2-aminoanthracene luminophore to yield a bifunctional magneto-luminescent nanosystem. The photoluminescence properties of the fluorophore are found modified by the confinement effect upon adsorption, while the magnetic behavior of PBA is preserved.

palavras-chave

METAL-ORGANIC FRAMEWORKS; FERROELECTRICITY

categoria

Chemistry; Science & Technology - Other Topics; Materials Science; Physics

autores

Mamontova, E; Long, J; Ferreira, RAS; Botas, AMP; Salles, F; Guari, Y; Carlos, LD; Larionova, J

nossos autores

agradecimentos

The authors thank the University of Montpellier, CNRS and PAC of ICGM. The Portugal-France bilateral action, PESSOA Program (Hubert Curien) Magneto-optical Multifunctional Nanoparticles (40773PE) is also acknowledged. This work was developed within the scope of the project CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (FCT Ref. UID/CTM/50011/2013) financed by national funds through the FCT/MEC and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement. A. M. P. Botas thanks FCT for a PhD fellowship (SFRH/BD/104789/2014).

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