Nitroprusside as a promising building block to assemble an organic-inorganic hybrid for thermo-responsive switching materials
authors Qiu, RG; Chen, XX; Huang, RK; Zhou, DD; Xu, WJ; Zhang, WX; Chen, XM
nationality International
journal CHEMICAL COMMUNICATIONS
keywords STRUCTURAL PHASE-TRANSITIONS; PROMINENT DIELECTRIC ANOMALIES; NEGATIVE THERMAL-EXPANSION; PEROVSKITE; CRYSTALS; CATIONS; STATE
abstract We present a new hybrid compound, namely (Me2NH2)[KFe(CN)(5)(NO)], possessing a unique nitroprusside-based inorganic host framework in 4-connected sra topology encapsulating organic guest cations. The flexible host-guest hydrogen bonds and synchronously deformed inorganic framework give rise to thermal-responsive switching behaviours on both thermal expansion and nonlinear optical properties during the phase transition at around room temperature.
publisher ROYAL SOC CHEMISTRY
issn 1359-7345
isbn 1364-548X
year published 2020
volume 56
issue 41
beginning page 5488
ending page 5491
digital object identifier (doi) 10.1039/d0cc01877e
web of science category Chemistry, Multidisciplinary
subject category Chemistry
unique article identifier WOS:000536127800002
  ciceco authors
  impact metrics
journal analysis (jcr 2019):
journal impact factor 5.996
5 year journal impact factor 5.818
category normalized journal impact factor percentile 81.073
dimensions (citation analysis):
altmetrics (social interaction):



 


Apoio

1suponsers_list_ciceco.jpg