Nitroprusside as a promising building block to assemble an organic-inorganic hybrid for thermo-responsive switching materials
| authors | Qiu, RG; Chen, XX; Huang, RK; Zhou, DD; Xu, WJ; Zhang, WX; Chen, XM |
| nationality | International |
| journal | CHEMICAL COMMUNICATIONS |
| keywords | STRUCTURAL PHASE-TRANSITIONS; PROMINENT DIELECTRIC ANOMALIES; NEGATIVE THERMAL-EXPANSION; PEROVSKITE; CRYSTALS; CATIONS; STATE |
| abstract | We present a new hybrid compound, namely (Me2NH2)[KFe(CN)(5)(NO)], possessing a unique nitroprusside-based inorganic host framework in 4-connected sra topology encapsulating organic guest cations. The flexible host-guest hydrogen bonds and synchronously deformed inorganic framework give rise to thermal-responsive switching behaviours on both thermal expansion and nonlinear optical properties during the phase transition at around room temperature. |
| publisher | ROYAL SOC CHEMISTRY |
| issn | 1359-7345 |
| isbn | 1364-548X |
| year published | 2020 |
| volume | 56 |
| issue | 41 |
| beginning page | 5488 |
| ending page | 5491 |
| digital object identifier (doi) | 10.1039/d0cc01877e |
| web of science category | Chemistry, Multidisciplinary |
| subject category | Chemistry |
| unique article identifier | WOS:000536127800002 |
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| journal analysis (jcr 2019): |
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| journal impact factor | 5.996 |
| 5 year journal impact factor | 5.818 |
| category normalized journal impact factor percentile | 81.073 |
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