resumo
Thin-film composite/nanocomposite (TFC/TFN) membranes count as the latest version of carbon capture membranes characterized by their excellent gas permeance, great selectivity, cost-effectiveness, and the ability to separately manage and tune the constituents of the individual layer. In this regard, Pebax((R))1657 embedded with synthesized Ag-BTC metal-organic frameworks (MOFs) was coated on the polyether imide (PEI) support layer to produce TFNs. To assess the impacts of Ag-BTC particles (carboxyl-rich surface particles) on the features of the constructed TFC/TFN membranes and their gas permeation qualities, several CO2/N-2 and CO2/CH4 separation experiments (mixed and pure gas testing) were carried out. Ag-BTC particles were distributed appropriately within the Pebax1657 matrix, improving the gas permeability (particularly for CO2) and enhancing CO2/N-2 and CO2/CH4 separation factors. A simultaneous increase in CO2 permeability and gas pair selectivities was observed with rising feed pressure. A 394.97 Barrer CO2 permeability and 38.20 CO2/N-2 and 21.25 CO2/CH4 selectivities were obtained for the TFN filled with 3 wt% Ag-BTC at 10 bar and 30 degrees C. A mixed gas test also showed a similar trend but lower values than a pure one. The results for the humidified conditions exhibited higher CO2 permselectivities in comparison with the dry gas given the water molecules facilitate the CO2 transportation through the Pebax (R) 1657 matrix. Finally, enhancing Ag-BTC filler content and increasing the input pressure provided excellent conditions for approaching Robeson's limit. (c) 2023 Institution of Chemical Engineers. Published by Elsevier Ltd. All rights reserved.
palavras-chave
MIXED-MATRIX MEMBRANES; HOLLOW-FIBER MEMBRANES; SEPARATION PERFORMANCE; POLYMERIC MEMBRANES; OXIDE NANOPARTICLES; CO2/N-2; LAYER; PEBAX; NANOCOMPOSITE; CO2/CH4
categoria
Engineering
autores
Nematollahi, MH; Carvalho, PJ; Coutinho, JAP; Abedini, R
nossos autores
Pedro J. Carvalho
Professor AuxiliarProjectos
CICECO - Aveiro Institute of Materials (UIDB/50011/2020)
CICECO - Aveiro Institute of Materials (UIDP/50011/2020)
Associated Laboratory CICECO-Aveiro Institute of Materials (LA/P/0006/2020)
agradecimentos
This work was partly developed within the scope of the Project CICECO-Aveiro Institute of Materials, UIDB/50011/2020, UIDP/50011/2020, and LA/P/0006/2020, financed by national funds through the Portuguese Foundation for Science and Technology FCT/MEC (PIDDAC) . M.H.N. thanks the University of Aveiro for his Ph.D. grant (BD/REIT/8743/2019) . The authors also acknowledge the Babol Noshirvani University of Technology for the financial support of this project (Grant No. BNUT/393054/2022) .