Microwave assisted synthesis of molybdenum and tungsten tetracarbonyl complexes with a pyrazolylpyridine ligand. Crystal structure of cis-[Mo(CO)4{ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate}]

resumo

We report the one-step syntheses in good yields of the complexes cis-[M(CO)(4)(PZPY)] {M = Mo, W; pzpy = ethyl[3-(2-pyridyl)-1-pyrazolyl]acetate} directly from the corresponding M(CO)(6) starting materials by using microwave-assisted heating and reaction times of either 30 s (M = Mo) or 15 min (M = W). The structure of the molybdenum tetracarbonyl complex was determined by single crystal X-ray diffraction. The compound is monomeric and the molybdenum atom has a highly distorted octahedral geometry. The close packing of the individual cis-[MO(CO)(4)(PZPY)] species is essentially driven by the need to fill the space effectively, closely mediated by weak C-H(...)O and pi(...)pi interactions.

palavras-chave

METAL-CARBONYL-COMPLEXES; BIOORGANOMETALLIC CHEMISTRY; ORGANOMETALLIC CHEMISTRY; CATALYTIC APPLICATIONS; MOLECULAR-STRUCTURE; HYDROGEN-BOND; PHARMACEUTICALS; SUBSTITUTION; DERIVATIVES; EPOXIDATION

categoria

Chemistry

autores

Coelho, AC; Paz, FAA; Klinowski, J; Pillinger, M; Goncalves, IS

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