2018
- M. M. Antunes, T. R. Amarante, A. A. Valente, F. A. Almeida Paz, I. S. Gonçalves, M. Pillinger
A Linear Trinuclear Oxidodiperoxido-molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization Reactions. ChemCatChem, 10, 2018, 2782. doi: 10.1002/cctc.201800232
2016
- P. Neves, T. R. Amarante, A. A. Valente, M. Pillinger, I. S. Gonçalves
Catalytic Application of an Octamolybdate Salt (H3biim)4[ß-Mo8O26] in Olefin Epoxidation (H2biim = 2,2’-biimidazole). Catalysis Letters, 146, 2016, 841-850. doi: 10.1007/s10562-016-1702-0
- T. R. Amarante, P. Neves, A. A. Valente, F. A. Almeida Paz, M. Pillinger, I. S. Gonçalves
Metal oxide-triazole as heterogeneous or reaction-induced self-separating catalysts, Journal of Catalysis, 340, 2016, 354-367. doi: 10.1016/j.jcat.2016.06.005
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T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz Crystal structure of an organic-inorganic supramolecular salt based on 4,4’-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cations and the ß-octamolybdate anion, Acta Crystallographic Section E, E72, 2016, 124-127. doi: 10.1107/S2056989015024524
2015
- T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz
Redetermination of the crystal structure of 3,5-dimethylpyrazolium ß-octamolybdate tetrahydrate, Acta Crystallographic Section E, E71, 2015, m244-m245. doi: 10.1107/S2056989015022823
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T. R. Amarante, M. M. Antunes, A. A. Valente, F. A. Almeida Paz, M. Pillinger, I. S. Gonçalves, Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine Hybrid, Inorganic Chemistry, 54, 2015, 9690-9703. doi: 10.1021/acs.inorgchem.5b00928
- P. Neves, A. C. Gomes, T. R. Amarante, F. A. Almeida Paz, M. Pillinger, I. S. Goçalves, A. A. Valente, Incorporation of a dioxomolybdenum(VI) complex in a Zr-IV-based Metal-Organic Framework and its application in catalytic olefin epoxidation, Microporous and Mesoporous Materials, 2015, 202, 106-114.
doi: 10.1016/j.micromeso.2014.09.046
2014
- T. R. Amarante, P. Neves, A. C. Gomes, M. M. Nolasco, P.R.-Claro, A C. Coelho, A. A. Valente, F. A. Almeida Paz, S. Smeets, L. B. McCusker, M. Pillinger, I. S. Gonçalves
Synthesis, Structural Elucidation, and Catalytic Properties in Olefin Epoxidation of the Polymeric Hybrid Material [Mo3O9(2-[3(5)-Pyrazolyl]pyridine)]n, Inorg. Chem., 2014, 53, 2652–2665. doi: 10.1021/ic403033j
- T. R. Amarante, P. Neves, F. A. Almeida Paz, A. A. Valente, M. Pillinger, I. S. Gonçalves, Investigation of dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivate as catalysts in olefin epoxidation, Dalton Trans., 2014, 43, 6059-6069. doi: 10.1039/c3dt52981a
2013
- T. R. Amarante, A. C. Gomes, P. Neves, F. A. Almeida Paz, A. A. Valente, M. Pillinger, I. S. Gonçalves
A Dinuclear Oxo-bridge Molybdenum(VI) complex containing a bidentate pyrazolylpyridine ligand: Structure, characterization and Catalytic performance for Olefin Epoxidation, Inorg. Chem. Commun., 32, 2013, 59-63.
- T. R. Amarante, P. Neves, A. A. Valente, F. A. Almeida Paz, A- N. Fitch, M. Pillinger, I. S. Gonçalves
Hydrothermal Synthesis, Crystal Structure, and Catalytic Potencial of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate Hybrid, Inorg. Chem., 52, 2013, 4618-4628. doi: 10.1021/ic400248m
2012
- S. Figueiredo, A. C. Gomes, P. Neves, T. R. Amarante, F. A. Almeida Paz, R. Soares, A. D. Lopes, A. A. Valente, M. Pillinger, I. S. Gonçalves
Shynthesis, Structural Elucidation, and Application of a Pyrazolylpyridine-Molybdenum Oxide Composite as a Heterogeneous Catalyst for Olefin Epoxidation, Inorg. Chem., 51, 2012, 8629-8635. doi: 10.1021/ic301405r
- T. R. Amarante, P. Neves, F. A. Almeida Paz, M. Pillinger, A. A. Valente, I. S. Gonçalves
A dinuclear oxomolybdenum(VI) complex, [Mo2O6(4,4’-di-tert-butyl-2,2’-bipyridine)2], displaying the [MoO2(μ-O)2MoO2]0 core, and its use as a catalyst in olefin epoxidation,Inorg. Chem. Commun., 20, 2012, 147-152. doi:10.1016/j.inoche.2012.02.038
- T. R. Amarante, P. Neves, C. Tomé, M. Abrantes, A. A. Valente, F. A. A. Paz, M. Pillinger, and I. S. Gonçalves
An Octanuclear Molybdenum(VI) Complex Containing Coordinatively Bound 4,4'-di-tert-Butyl-2,2'-Bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: Synthesis, Structure, and Catalytic Epoxidation of Bio-Derived Olefins, Inorg. Chem., 51, 2012,3666-3676. doi: 10.1021/ic202640a
2011
- T. R. Amarante, J. A. Fernandes, I. S. Gonçalves, F. A. Almeida Paz
Tris(4,4'-di-tert-butyl-2,2-bipyridine-κ2N,N')molybdenum(II)(μ6-oxo)-dodecakis(μ2-oxo)-hexaoxohexamolybdate(VI)acetonitriletetrasolvate, Acta Crystallogr., Sect. E: Struct. Rep. Online, E67, 2011, m1828-m1829. doi:10.1107/S1600536811049385
- T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz
Di-tert-butyl-2,2’-dipirydine chloride, Acta Crystallogr., Sect. E: Struct. Rep. Online, E67, 2011, o1903-o1904. doi:10.1107/S1600536811025529
- P. Neves, T. R. Amarante, A. C. Gomes, A. C. Coelho, S. Gago, M. Pillinger, I. S. Gonçalves, C. M. Silva, A. A. Valente
Heterogeneous oxidation catalysts formed in situ from molybdenum tetracarbonyl complexes and tert-butyl hydroperoxide. Applied Catalysis A: General,2011, 395, 71-77. doi:10.1016/j.apcata.2011.01.029
2010
- M. Abrantes, T. R. Amarante, M. M. Antunes, S. Gago, F. A. Almeida Paz, I. Margiolaki, A. E. Rodrigues, M. Pillinger, A. A. Valente, I. S. Gonçalves
Synthesis, Structural and Catalytic Performance in Olefin Epoxidation of a New Molybdenum Oxide/Bipyridine Hybrid Material: {[MoO3(bipy)][MoO3(H2O)]}n, Inorganic Chemistry, 2010, 49, 6865-6873. doi: 10.1021/ic100479a
- T. R. Amarante, Patrícia N., A. C. Coelho, S. Gago, A. A. Valente, F. A. Almeida Paz, M. Pillinger, and I. S. Gonçalves
Investigation of molybdenum tetracarbonyl complexes as precursors to MoVI catalysts for the epoxidation of olefins, Organometallics, 2010, 29, 883-892.
2009
- I. S. Gonçalves, A. D. Lopes, T. R. Amarante, F. A. Almeida Paz, N. J. O. Silva, M. Pillinger, S. Gago, F. Palácio, E. F. Kühn, C. C. Romão
Heterometallic Complexes Involving Iron(II) and Rhenium(VII) Centers Connected by u-Oxido Bridges: Synthesis, Structures and Magnetic Properties. Dalton Trans., 2009, 10199-10207.
- T. R. Amarante, F. A. Almeida Paz, S. Gago, I. S. Gonçalves, M. Pillinger, A. E. Rodrigues, M. Abrantes
Microwave-Assisted Synthesis and Crystal Structure of Oxo(diperoxo)(4,4'-di-tert-butyl-2,2'-bipyridine)molybdenum(VI). Molecules, 14, 2009, 3610-3620. doi:10.3390/molecules14093610
- T. R. Amarante, S. Figueiredo, A. D. Lopes, I. S. Gonçalves, F. A. Almeida Paz
4,4'-Di-tert-butyl-2,2'-dipyridyl. Acta Crystallographica Section E: Struture Reports Online, E65, 2009, o2047. doi:10.1107/S1600536809029109
- T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz
2-(1H-Pyrazol-3-yl)pyridinium chloride monohydrate. Acta Crystallographica Section E: Structure Reports Online, E65, 2009, o1962-o1963. doi:10.1107/S1600536809028402
- T. R. Amarante, I. S. Gonçalves, F. A. Almeida Paz
Mo4(n3-allyl)4Cl2(OH)2(CO)8: the first cubane-type Mo2+ organometallic complex with u3-OH and u3-Cl bridges. Acta Crystallographica Section C: Crystal Structures Comunications, 65, 2009, m168-m170. doi:10.1107/S0108270109009512
2008
- T. R. Amarante, A. C. Coelho, J. Klinowski, I. S. Gonçalves, F. A. Almeida Paz
1-Hydroxy-1,1,3,3,3-pentaphenyldisiloxane, [Si2O(OH)(Ph)5], at 150 K. Acta Crystallographica Section E: Struture Reports Online, E64, 2008, o239-o239. doi:10.1107/S1600536807064987
- A. C. Coelho, T. R. Amarante, J. Klinowski, I. S. Gonçalves, F. A. Almeida Paz
1-Hydroxy-1,1,3,3,3-pentaphenyl- disiloxane, [Si2O(OH)(Ph)5] at 100 K. Acta Crystallographica Section E: Structure Reports Online, E64, 2008, o237-o238. doi:10.1107/S1600536807064975
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Heterogeneous catalysis with an organic-inorganic hybrid based on MoO3 chains decorated with 2,2 '-biimidazole ligandsAmarante, TR; Neves, P; Paz, FAA; Gomes, AC; Pillinger, M; Valente, AA; Goncalves, IS 2021, CATALYSIS SCIENCE & TECHNOLOGY, 11, 6, 2214-2228.
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Vanadoborates: cluster-based architectures, preparation and propertiesLiu, X; Zhou, J; Amarante, TR; Paz, FAA; Fu, LS 2021, DALTON TRANSACTIONS, 50, 5, 1550-1568.
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A Copper(I)-Thioarsenate(III) Inorganic Framework Directed by [Ni(en)(3)](2+)Liu, X; Zhou, J; Huang, L; Xiao, HP; Amarante, TR; Paz, FAA; Xiang, B; Fu, LS 2021, INORGANIC CHEMISTRY, 60, 9, 6813-6819.
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A Comparative Study of Molybdenum Carbonyl and Oxomolybdenum Derivatives Bearing 1,2,3-Triazole or 1,2,4-Triazole in Catalytic Olefin EpoxidationNogueira, LS; Neves, P; Gomes, AC; Amarante, TA; Paz, FAA; Valente, AA; Goncalves, IS; Pillinger, M 2019, MOLECULES, 24, 1,
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A Linear Trinuclear Oxidodiperoxido-molybdenum(VI) Complex with Single Triazole Bridges: Catalytic Activity in Epoxidation, Alcoholysis, and Acetalization ReactionsAntunes, MM; Amarante, TR; Valente, AA; Paz, FAA; Goncalves, IS; Pillinger, M 2018, CHEMCATCHEM, 10, 13, 2782-2791.
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Catalytic Application of an Octamolybdate Salt (H(3)biim)(4)[beta-Mo8O26] in Olefin Epoxidation (H(2)biim=2,2'-biimidazole)Neves, P; Amarante, TR; Valente, AA; Pillinger, M; Goncalves, IS 2016, CATALYSIS LETTERS, 146, 4, 841-850.
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Crystal structure of an organic-inorganic supramolecular salt based on a 4,4 '-methylenebis(3,5-dimethyl-1H-pyrazol-2-ium) cation and a beta-octamolybdate anionAmarante, TR; Goncalves, IS; Paz, FAA 2016, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 72, 124-+.
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Metal oxide-triazole hybrids as heterogeneous or reaction-induced self-separating catalystsAmarante, TR; Neves, P; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS 2016, JOURNAL OF CATALYSIS, 340, 354-367.
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Redetermination of the crystal structure of 3,5-dimethylpyrazolium beta-octamolybdate tetrahydrateAmarante, TR; Goncalves, IS; Paz, FAA 2015, ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 71, M244-+.
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Crystal Structure and Catalytic Behavior in Olefin Epoxidation of a One-Dimensional Tungsten Oxide/Bipyridine HybridAmarante, TR; Antunes, MM; Valente, AA; Paz, FAA; Pillinger, M; Goncalves, IS 2015, INORGANIC CHEMISTRY, 54, 20, 9690-9703.
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Incorporation of a dioxomolybdenum(VI) complex in a Zr-IV-based Metal-Organic Framework and its application in catalytic olefin epoxidationNeves, P; Gomes, AC; Amarante, TR; Paz, FAA; Pillinger, M; Goncalves, IS; Valente, AA 2015, MICROPOROUS AND MESOPOROUS MATERIALS, 202, 106-114.
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Synthesis, Structural Elucidation, and Catalytic Properties in Olefin Epoxidation of the Polymeric Hybrid Material [Mo3O9(2-[3(5)-Pyrazolyl]pyridine)](n)Amarante, TR; Neves, P; Gomes, AC; Nolasco, MM; Ribeiro-Claro, P; Coelho, AC; Valente, AA; Paz, FAA; Smeets, S; McCusker, LB; Pillinger, M; Goncalves, IS 2014, INORGANIC CHEMISTRY, 53, 5, 2652-2665.
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Investigation of a dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivative as catalysts in olefin epoxidationAmarante, TR; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS 2014, DALTON TRANSACTIONS, 43, 16, 6059-6069.
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A dinuclear oxo-bridged molybdenum(VI) complex containing a bidentate pyrazolylpyridine ligand: Structure, characterization and catalytic performance for olefin epoxidationAmarante, TR; Gomes, AC; Neves, P; Paz, FAA; Valente, AA; Pillinger, M; Goncalves, IS 2013, INORGANIC CHEMISTRY COMMUNICATIONS, 32, 59-63.
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Hydrothermal Synthesis, Crystal Structure, and Catalytic Potential of a One-Dimensional Molybdenum Oxide/Bipyridinedicarboxylate HybridAmarante, TR; Neves, P; Valente, AA; Paz, FAA; Fitch, AN; Pillinger, M; Goncalves, IS 2013, INORGANIC CHEMISTRY, 52, 8, 4618-4628.
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