Mixed Cu(II)-Bi(III) metal organic framework with a 2D inorganic subnetwork and its catalytic activity

abstract

The very dense (d = 4.359 g cm(-3)) three dimensional (3D) hybrid heterometallic framework Bi3O2Cu(OH)(pdc)(2) (pdc(3-):3,5-pyrazoledicarboxylate), 1, features a 2D inorganic subnetwork representing an unprecedented topological type, and is an effective catalyst for the diastereoselective synthesis of E-alpha,beta-unsaturated ketones.

keywords

COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; BISMUTH SUBSALICYLATE; MOLECULAR PRECURSORS; CRYSTAL-STRUCTURE; SALICYLATE; COMPLEXES; ION

subject category

Chemistry; Crystallography

authors

Shi, FN; Silva, AR; Yang, TH; Rocha, J

our authors

acknowledgements

We thank FCT, FEDER, QREN, COMPETE, (PEst-C/CTM/LA0011/2011), Rede Nacional de RMN, and grant SFRH/BPD/74582/2010, F.-N. SHI and Ana acknowledge FCT for Ciencia 2007, 2008 program and project PTDC/CTM-NAN/119994/2010.

Share this project:

Related Publications

We use cookies for marketing activities and to offer you a better experience. By clicking “Accept Cookies” you agree with our cookie policy. Read about how we use cookies by clicking "Privacy and Cookie Policy".