abstract
A thorough vibrational spectroscopy and molecular modeling study on poly(ethylene 2,5-furandicarboxylate) (PEF) explores its conformational preferences, in the amorphous and crystalline regions, while clarifying structure property correlations. Despite the increasing relevance of PEF as a sustainable polymer, some of its unique characteristics are not yet fully understood and benefit from a deeper comprehension of its microstructure and intermolecular bonding. Results show that in the amorphous domains, where intermolecular interactions are weak, PEF chains favor a helical conformation. Prior to crystallization, polymeric chains undergo internal rotations extending their shape in a zigzag pattern-an energetically unfavorable geometry which is stabilized by C-H center dot center dot center dot O bonds among adjacent chain segments. The zigzag conformation is the crystalline motif present in the a and beta PEF polymorphs. The energy difference among the amorphous and crystalline chains of PEF is higher than in PET poly(ethylene terephthalate) and contributes to PEF's higher crystallization temperature. The 3D arrangement of PEF chains was probed using inelastic neutron scattering (INS) spectroscopy and periodic DFT calculations. Comparing the INS spectra of PEF with that of poly(ethylene terephthalate) (PET) revealed structure-property correlations. Several low-frequency vibrational modes support the current view that PEF chains are less flexible than those of PET, posing greater resistance to gas penetration and resulting in enhanced barrier properties. The vibrational assignment of PEF's INS spectrum is a useful guide for future studies on advanced materials based on PEF.
keywords
BIOBASED POLY(ETHYLENE 2,5-FURANDICARBOXYLATE); INELASTIC NEUTRON-SCATTERING; DENSITY-FUNCTIONAL THEORY; O HYDROGEN-BONDS; RENEWABLE RESOURCES; VIBRATIONAL SPECTROSCOPY; POLY(ETHYLENE-TEREPHTHALATE) FILMS; POLYETHYLENE TEREPHTHALATE; NONISOTHERMAL CRYSTALLIZATION; THERMAL-PROPERTIES
subject category
Polymer Science
authors
Araujo, CF; Nolasco, MM; Ribeiro-Claro, PJA; Rudic, S; Silvestre, AJD; Vaz, PD; Sousa, AF
our authors
Groups
G4 - Renewable Materials and Circular Economy
G6 - Virtual Materials and Artificial Intelligence
Projects
CICECO - Aveiro Institute of Materials (UID/CTM/50011/2013)
Projeto de Investigação Exploratória: Mariela Nolasco (IF/01468/2015)
Other
Cover
Mediaacknowledgements
This work was developed within the scope of the project CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (FCT ref. UID/CTM/50011/2013), financed by Portuguese funds through the FCT/MEC and when appropriate cofinanced by FEDER under the PT2020 Partnership Agreement. FCT and POPH/FSE are gratefully acknowledged for funding a postdoctoral grant to A.F.S. (SFRH/BPD/73383/2010). FCT is gratefully acknowledged for funding a PhD grant to C.F.A. (SFRH/BD/129040/2017) and a researcher contract to M.M.N. (IF/01468/2015) under the program IF 2015. The STFC Rutherford Appleton Laboratory is thanked for access to neutron beam facilities. CASTEP calculations were made possible due to the computing resources provided by STFC Scientific Computing Department's SCARF cluster.