Modeling 4f–4f intensity parameters as a function of structural distortions in Ln(2,2′-bipyridine-1,1′-dioxide)4(ClO4)3 complexes (Ln=Pr3+, Nd3+)

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abstract

This work reports on the influence of structural distortions on 4 f-4 f intensity parameters. These distortions in the first coordination sphere were applied to two complexes with similar structures, Ln(bpyO2)4(ClO4)3 (Ln=Pr3+, Nd3+ ions and bpyO2=2,2’-bipyridine-1,1'-dioxide). The 4 f-4 f intensity theory and the PM3/Sparkle model were used. It is concluded that larger distortions are predicted in the case of the Pr complex, and that this point might contribute to the rationalization of the much higher values of the Ωλ intensity parameters in the Pr complex than in the Nd one.

authors

A.N. Carneiro, E. Huskowska, P. Gawryszewska, J. Legendziewicz, O.L. Malta

our authors

foto Albano Neto Carneiro Neto

Albano Neto Carneiro Neto

Junior Researcher

Groups

G2 - Photonic, Electronic and Magnetic Materials

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Publication Details

type
Journal Article
year
2016
journal
Journal of Luminescence
volume
169
digital object identifier
10.1016/j.jlumin.2015.02.028

Journal Metrics (JCR 2019)

Journal Impact Factor
3.28
Journal Impact Factor (5 yrs)
2.824
category normalized journal percentile
78.866

Citations

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