Furfural Oxidation with Hydrogen Peroxide Over ZSM-5 Based Micro-Mesoporous Aluminosilicates

abstract

Micro-mesoporous aluminosilicates based on ZSM-5 zeolite, obtained by a dual template method, as well as in the presence of a dual-functional template (i.e. a Gemini-type surfactant), were tested in the oxidation of furfural with hydrogen peroxide. Even substantial changes in acidity and porosity of the catalysts result in minor variations of selectivity towards the desired products. Application of the synthesized zeolite-based materials in the oxidation of furfural with hydrogen peroxide leads to formation of 2(5H)-furanone (yield up to 28.5%) and succinic acid (up to 19.5%) as the main C4 reaction products. The kinetic model developed previously to treat the results for oxidation of furfural over sulfated zirconia was able to describe the data also for micro-mesoporous aluminosilicates. [GRAPHICS] .

keywords

SUCCINIC ACID; MFI ZEOLITE; CATALYST; TRANSFORMATION; TEMPERATURE; ADSORPTION; NANOSHEETS; METHANOL; SYSTEMS

subject category

Chemistry

authors

Shcherban, ND; Barakov, RY; Sergiienko, SA; Eranen, K; Warna, J; Murzin, DY

our authors

acknowledgements

Open access funding provided by Abo Akademi University (ABO).

Share this project:

Related Publications

We use cookies for marketing activities and to offer you a better experience. By clicking “Accept Cookies” you agree with our cookie policy. Read about how we use cookies by clicking "Privacy and Cookie Policy".