Palladium and Molybdenum Complexes of the Heteroleptic Organostannylene [2,6-(Me2NCH2)(2)C6H3]SnCl

abstract

The synthesis and molecular structures are reported for the transition metal heteroleptic organo-stannylene complexes {[2,6-(Me2NCH2)(2)C6H3]SnCl}(C5H5)(CO)(2)MoCl (6) and {[2,6-(Me2NC-H-2)(2)C6H3]Sn(OAc)}Pd(Cl)[2-(Me2NCH2)C6H4] (7). It is shown that the intramolecularly coordinated heteroleptic organostannylene [2,6-(Me2NCH2)(2)C6H3]SnCl undergoes a redox-type reaction with Pd(PPh3)(4) to give cis- [2,6-(Me2NCH2)(2)C6H3]SnCl}(2)PdCl2.

keywords

STANNA-CLOSO-DODECABORATE; METAL-NITROSYL COMPLEXES; X-RAY-STRUCTURE; ASYMMETRIC HYDROFORMYLATION; CRYSTAL-STRUCTURE; COORDINATION CHEMISTRY; MOLECULAR-STRUCTURES; ENANTIOSELECTIVE HYDROFORMYLATION; DONOR STABILIZATION; CARBONYL LIGANDS

subject category

Chemistry

authors

Martincova, J; Jambor, R; Schurmann, M; Jurkschat, K; Honzicek, J; Paz, FAA

our authors

acknowledgements

The authors thank the Grant Agency of the Czech Republic (project no. GA370468), the Ministry of Education of the Czech Republic (project nos. VZ0021627501 and LC523), and the Erasmus Program of the EU and Technische Universitat Dortmund for financial support.

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