Magnetic Behaviour of Perovskite Compositions Derived from BiFeO3
authors Salak, AN; Cardoso, JPV; Vieira, JM; Shvartsman, VV; Khalyavin, DD; Fertman, EL; Fedorchenko, AV; Pushkarev, AV; Radyush, YV; Olekhnovich, NM; Tarasenko, R; Feher, A; Cizmar, E
nationality International
journal MAGNETOCHEMISTRY
author keywords atomic substitution; Neel temperature; G-type antiferromagnetic; weak ferromagnetism; collinear magnetic ground state
keywords CRYSTAL-STRUCTURE; PHASE-TRANSITIONS; POLAR; POLARIZATION; BOUNDARY; AMBIENT
abstract The phase content and sequence, the crystal structure, and the magnetic properties of perovskite solid solutions of the (1-y)BiFeO3-yBiZn(0.5)Ti(0.5)O(3) series (0.05 & LE; y & LE; 0.90) synthesized under high pressure have been studied. Two perovskite phases, namely the rhombohedral R3c and the tetragonal P4mm, which correspond to the structural types of the end members, BiFeO3 and BiZn0.5Ti0.5O3, respectively, were revealed in the as-synthesized samples. The rhombohedral and the tetragonal phases were found to coexist in the compositional range of 0.30 & LE; y & LE; 0.90. Magnetic properties of the BiFe1-y[Zn0.5Ti0.5](y)O-3 ceramics with y < 0.30 were measured as a function of temperature. The obtained compositional variations of the normalized unit-cell volume and the Neel temperature of the BiFe1-y[Zn0.5Ti0.5](y)O-3 perovskites in the range of their rhombohedral phase were compared with the respective dependences for the BiFe1-yBy3+O3 perovskites (where B3+ = Ga, Co, Mn, Cr, and Sc). The role of the high-pressure synthesis in the formation of the antiferromagnetic states different from the modulated cycloidal one characteristic of the parent BiFeO3 is discussed.
publisher MDPI
isbn 2312-7481
year published 2021
volume 7
issue 11
digital object identifier (doi) 10.3390/magnetochemistry7110151
web of science category 12
subject category Chemistry, Inorganic & Nuclear; Chemistry, Physical; Materials Science, Multidisciplinary
unique article identifier WOS:000727417000001
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