abstract
This work presents a new type of feed-back active coating with inhibitor-containing reserviors for corrosion protection of metallic substrates. The reservoirs are composed of stratified layers of oppositely charged polyelectrolytes film with the entrapped corrosion inhibitor is constucted by sequential spray-coating deposition of water solutions of poly(ethyleneimine), poly(sodium styrenesulfonate) and 8-hydroxyquiniline on the top of the sol-gel coating. The active corrosion protection of AA2024 alloy coated with SiO2/ZrO2 sol-gel film and modified by polyelectrolytes is demonstrated by electrochemical impedance spectroscopy and scanning vibrating electrode technique. The results obtained here show that polyelectrolyte films deposited atop of the hybrid sol-gel coating on AA2024 alloy remarkably improve the long-tern protection performance providing additional "intelligent" anticorrosion effect that results from delivery of inhibiting species "on demand". This becomes possible since the configuration of the polyelectrolyte molecules depends on the presence of H+ ions making the polyelectrolyte film sensitive the configuration of the polyelectrolyte molecules depends on the presence of H+ ions making the polyelectrolyte film sensitive to the pH of the surrounding solution. The source of local pH changes is the corrosion process starting in the micro- and nano-defects leading to increased permeability of the polyelectrolyte reservoir and, consequently, to controllable release of entrapped inhibitor.
keywords
LAYER POLYMER-FILMS; POLYELECTROLYTE MULTILAYERS; ANTICORROSION COATINGS; IMPEDANCE SPECTROSCOPY; WEAK POLYELECTROLYTES; LOCALIZED CORROSION; NANOCONTAINERS; COMPOSITES; INHIBITION; MECHANISM
subject category
Chemistry; Science & Technology - Other Topics; Materials Science; Physics
authors
Lamaka, SV; Shchukin, DG; Andreeva, DV; Zheludkevich, ML; Mohwald, H; Ferreira, MGS
our authors
Mário Guerreiro Silva Ferreira
Retired Professor
Mikhail Zheludkevich
Invited Principal Researcheracknowledgements
The research was supported by DAAD/GRICES the German/Portuguese collaboration project (D/06/12931). D. G. S. and D. V. A. also thank the support of NanoFutur program of the German Ministry of Science and Education (BMBF). FCT project REEQ/719/CTM/2005-ECOFUELS is gratefully acknowledged. S. V. L. would like to thank Marta Ferro and Prof. Augusto Lopes for their help in mastering SEM/EDS skills.