abstract
Carboxylate-intercalated (terephthalate, TA and oxalate, ox) layered double hydroxides (LDHs) are aged under a microwave-hydrothermal treatment. The influence of the nature of the interlayer anion during the ageing process is studied. Characterization results show that the microwave-hydrothermal method can be extended to synthesize LDHs with anions different than carbonate, like TA. LDH-TA compounds are stable under microwave irradiation for increasing periods of time and the solids show an improved order both in the layers and in the interlayer region as evidenced by powder X-ray diffraction (PXRD), Al-27 MAS NMR and FT-IR spectroscopy. Furthermore, cleaning of the surface through removal of some organic species adsorbed on the surface of the particles also occurs during the microwave-hydrothermal treatment. Conversely, although the expected increase in crystallinity is observed in LDH-ox samples, the side-reaction between Al3+ and ox is also enhanced under microwave irradiation, and a partial destruction of the structure takes place with an increase in the M2+/M3+ ratio and consequent modification of the cell parameters. (C) 2008 Elsevier Inc. All rights reserved.
keywords
HYDROTALCITE-LIKE COMPOUNDS; INTERLAYER ARRANGEMENT; ANION-EXCHANGE; TEREPHTHALATE; ZN; AL; SIMULATION; PRECURSORS; DYNAMICS; RELEASE
subject category
Chemistry
authors
Benito, P; Labajos, FM; Mafra, L; Rocha, J; Rives, V
our authors
João Rocha
Full Professor
Luís Mafra
Principal Researcheracknowledgements
Authors thank financial support from EFRD and MEC (Grant 2006-10800-C02-01). PB acknowledges a grant from junta de Castilla y Leon.