High-pressure zinc oxysulphide phases in the ZnO-ZnS system

authors	Salak, AN; Ignatenko, OV; Zhaludkevich, AL; Lisenkov, AD; Starykevich, M; Zheludkevich, ML; Ferreira, MGS
nationality	International
journal	PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
author keywords	high pressure; wurtzite; X-ray diffraction; zincblende
keywords	FILMS; DIFFRACTION; PARAMETERS; DEPOSITION; RICH
abstract	Wurtzite-zincblende mixture, ZnO-ZnS (1:1wt.%), was thermally treated at 5GPa in order to explore a possible mutual solubility of the end members and formation of zinc oxysulphide phases under high pressure. The data on phase content, crystal structure, and microstructure from the X-ray diffraction and the scanning electron microscopy studies of the obtained compacts (ceramics) were compared and analyzed. It was found that as temperature is increased, the following processes occur in the ZnO-ZnS mixture under pressure: release of the mechanical stresses (between about 300 and 700 degrees C), recrystallization of the initial wurtzite and zincblende phases (700-900 degrees C), reaction between the end members (above approximate to 900 degrees C) that results in formation of mixed oxysulphides based on ZnO and ZnS, respectively, with the mutual solubility rate of about 8mol.%.
publisher	WILEY-V C H VERLAG GMBH
issn	1862-6300
year published	2015
volume	212
issue	4
beginning page	791
ending page	795
digital object identifier (doi)	10.1002/pssa.201431820
web of science category	Materials Science, Multidisciplinary; Physics, Applied; Physics, Condensed Matter
subject category	Materials Science; Physics
unique article identifier	WOS:000352820100013