funding type |
European Comission |
programme |
ERC-2019-COG - ERC Consolidator Grant |
acronym/
reference |
NMR4CO2 |
alternative reference |
865974 |
research group(s) |
1 - inorganic functional nanomaterials and organic-inorganic hybrids; |
department |
Chemistry (DQ) |
execution dates |
2020-06-01 - 2025-05-31 (
60 Months )
|
abstract/
keywords |
Reaching a record high of 32.5 gigatonnes in 2017, global CO2 emissions from fossil fuel combustion continue to increase. Adsorption is considered a viable technology to reduce CO2 emissions. Because of its lower regeneration cost, amine-modified porous silica (AMPS) is the most promising CO2-adsorbent material for replacing the decades-old liquid amine-scrubbing technology. However, a molecular-scale understanding of the CO2-AMPS adsorption process remains elusive, hindering progress in the design of improved sorbents. The EU-funded NMR4CO2 project addresses this need, using – for the first time – state-of-the-art surface-enhanced nuclear magnetic resonance to study the chemistry of acidic gases (mainly CO2) adsorbed on AMPS and of gas-solid interfaces using simulated industrial gas mixtures. |
coordinator
/local pi |
Luís Mafra |
ciceco status |
Coordinator |
proponent institution |
Universidade de Aveiro (UA) |
partner institution(s) |
no
|
industrial partner(s) |
no |
international partner(s) |
no |
total budget |
1.999.793€
|
ciceco budget |
1.999.793€
|
project code |
3.89.318 |
link |
https://cordis.europa.eu/project/id/865974
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“Hidden” CO2 in Amine-Modified Porous Silicas Enables Full Quantitative NMR Identification of Physi- and Chemisorbed CO2 SpeciesRicardo Vieira, Ildefonso Marin-Montesinos, João Pereira, Rita Fonseca, Marina Ilkaeva, Mariana Sardo, and Luís Mafra 2021, The Journal of Physical Chemistry C, 125, 27, 14797-14806.
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Hidden CO2 in Amine-Modified Porous Silicas Enables Full Quantitative NMR Identification of Physi- and Chemisorbed CO2 SpeciesVieira, R; Marin-Montesinos, I; Pereira, J; Fonseca, R; Ilkaeva, M; Sardo, M; Mafra, L 2021, JOURNAL OF PHYSICAL CHEMISTRY C, 125, 27, 14797-14806.
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Unravelling moisture-induced CO2 chemisorption mechanisms in amine-modified sorbents at the molecular scaleSardo, M; Afonso, R; Juzkow, J; Pacheco, M; Bordonhos, M; Pinto, ML; Gomes, JRB; Mafra, L 2021, JOURNAL OF MATERIALS CHEMISTRY A, 9, 9, 5542-5555.
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What Is Being Measured with P-Bearing NMR Probe Molecules Adsorbed on Zeolites?Bornes, C; Fischer, M; Amelse, JA; Geraldes, CFGC; Rocha, J; Mafra, L 2021, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 143, 34, 13616-13623.
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2D Layered Dipeptide Crystals for Piezoelectric ApplicationsZelenovskii, PS; Romanyuk, K; Liberato, MS; Brandao, P; Ferreira, FF; Kopyl, S; Mafra, LM; Alves, WA; Kholkin, AL 2021, ADVANCED FUNCTIONAL MATERIALS, 31, 43,
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