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Equipa
Luís Mafra
Investigador PrincipalDescrição
Reaching a record high of 32.5 gigatonnes in 2017, global CO2 emissions from fossil fuel combustion continue to increase. Adsorption is considered a viable technology to reduce CO2 emissions. Because of its lower regeneration cost, amine-modified porous silica (AMPS) is the most promising CO2-adsorbent material for replacing the decades-old liquid amine-scrubbing technology. However, a molecular-scale understanding of the CO2-AMPS adsorption process remains elusive, hindering progress in the design of improved sorbents. The EU-funded NMR4CO2 project addresses this need, using – for the first time – state-of-the-art surface-enhanced nuclear magnetic resonance to study the chemistry of acidic gases (mainly CO2) adsorbed on AMPS and of gas-solid interfaces using simulated industrial gas mixtures.
Coordenador
Coordenação
Universidade de Aveiro (UA)
Participantes
Não
Resultados
Understanding CO2 adsorption mechanisms in porous adsorbents: A solid-state NMR survey
Daniel Pereira, Rita Fonseca, Ildefonso Marin-Montesinos, Mariana Sardo, Luís MafraOne-Shot Resin 3D-Printed Stators for Low-Cost Fabrication of Magic-Angle Spinning NMR Probeheads
Daniel Pereira, Mariana Sardo, Ildefonso Marín-Montesinos, an Luís MafraExploring Molecular Dynamics of Adsorbed CO2 Species in Amine- Modified Porous Silica by Solid-State NMR Relaxation
Fonseca, R; Vieira, R; Sardo, M; Marin-Montesinos, I; Mafra, LMoisture effect on the separation of CO2/CH4 mixtures with amine-functionalised porous silicas
Pacheco, M; Bordonhos, M; Sardo, M; Afonso, R; Gomes, JRB; Mafra, L; Pinto, MLHidden CO2 in Amine-Modified Porous Silicas Enables Full Quantitative NMR Identification of Physi- and Chemisorbed CO2 Species
Vieira, R; Marin-Montesinos, I; Pereira, J; Fonseca, R; Ilkaeva, M; Sardo, M; Mafra, LUnravelling moisture-induced CO2 chemisorption mechanisms in amine-modified sorbents at the molecular scale
Sardo, M; Afonso, R; Juzkow, J; Pacheco, M; Bordonhos, M; Pinto, ML; Gomes, JRB; Mafra, LWhat Is Being Measured with P-Bearing NMR Probe Molecules Adsorbed on Zeolites?
Bornes, C; Fischer, M; Amelse, JA; Geraldes, CFGC; Rocha, J; Mafra, L2D Layered Dipeptide Crystals for Piezoelectric Applications
Zelenovskii, PS; Romanyuk, K; Liberato, MS; Brandao, P; Ferreira, FF; Kopyl, S; Mafra, LM; Alves, WA; Kholkin, ALFinanciadores
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UID/CTM/50011/2013